The effect of separating layer between reacting media and molding template on the porous structure of combustion synthesized Ni-Al intermetallics

This research focuses on identifying conditions under which porous intermetallics with a welded granular structure comprised of mm-sized spheroidal alloy elements can be directly obtained by combustion synthesis using mu m-sized metal powders as starting reagents. The heat loss of reacting medium to...

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Bibliographic Details
Published in:Materials letters Vol. 314. P. 131854
Other Authors: Pichugin, Nikita, Kirdyashkin, A., Kitler, V. D., Maznoy, Anatoly
Format: Article
Language:English
Subjects:
Online Access:http://vital.lib.tsu.ru/vital/access/manager/Repository/koha:001001524
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245 1 4 |a The effect of separating layer between reacting media and molding template on the porous structure of combustion synthesized Ni-Al intermetallics  |c N. Pichugin, A. Kirdyashkin, V. D. Kitler, A. Maznoy 
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520 3 |a This research focuses on identifying conditions under which porous intermetallics with a welded granular structure comprised of mm-sized spheroidal alloy elements can be directly obtained by combustion synthesis using mu m-sized metal powders as starting reagents. The heat loss of reacting medium to a molding template used to shape a powder mixture of reagents significantly reduce the size of the alloy elements in manufactured material, especially near the mixture/template interface. One possible solution to this problem is to employ a separating layer between the powder mixture and the molding template. The effect of separating layers, both chemically inert (ceramic-based) and active (cellulose-based), on the size of Ni-Al elements has been experimentally studied. It was found that notable structure modification can be achieved by using cellulose-based separating layers. The carbon-containing products released during cellulose pyrolysis interact with the reacting medium and promote the coalescence of metal melts. Changing the thickness of the cellulose-based separating layer is an easy way to control the porous structure and permeation properties of combustion synthesized Ni-Al-based intermetallics, which makes them relevant for practical application. 
653 |a пористые интерметаллиды 
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700 1 |a Pichugin, Nikita 
700 1 |a Kirdyashkin, A. 
700 1 |a Kitler, V. D. 
700 1 |a Maznoy, Anatoly 
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