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230529|2022 sz s a eng d |
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|a 10.3390/ma15051804
|2 doi
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|a koha001002552
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|a RU-ToGU
|b rus
|c RU-ToGU
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|a Stability of octadecyltrimethoxysilane-based coatings on aluminum alloy surface
|c A. Y. Zhizhchenko, A. V. Shabalina, A. A. Aljulaih [et al.]
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|a Текст
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|a электронный
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|a Библиогр.: 54 назв.
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|a Long-term stability in contact with water of organosilane layers formed by octadecyltrimethoxysilane (ODTMS) on polished aluminum alloy (AA2024) through dip-coating was studied by combining SEM, water contact angle measurements, and X-ray photoelectron spectroscopy. Similar organosilane layers were formed on AA2024 coated with permanganate conversion coating, 1,2-bis(triethoxysilyl)ethane (BTSE) and hydrated SiOx as under-layers, after which their long-term durability was also tested. During immersion in water for about one month, all the samples exhibited a decrease in hydrophobicity, implying the prepared organosilane layer was not stable over time, gradually hydrolyzing and letting water interact with the underlying layer. In parallel, SEM images of one-layer samples taken after immersion showed clear signs of local electrochemical corrosion, while XPS analysis confirmed a loss of silicon from the surface layer. The highest stability over time was demonstrated by a one-layer sample prepared in an ethanol/water bath for 5 min and by a similar ODTMS layer prepared on hydrated MnOx as an under-layer.
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|a октадецилтриметоксисилан
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|a смачиваемость
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| 653 |
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|a алюминиевые сплавы
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| 653 |
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|a поверхностная коррозия
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| 655 |
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|a статьи в журналах
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|a Zhizhchenko, Alexey Y.
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1 |
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|a Shabalina, Anastasiia V.
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1 |
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|a Aljulaih, Ali A.
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1 |
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|a Gurbatov, Stanislav O.
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1 |
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|a Kuchmizhak, Aleksandr A.
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|a Iwamori, Satoru
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|a Kulinich, Sergei A.
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| 773 |
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|t Materials
|d 2022
|g Vol. 15, № 5. P. 1804 (1-14)
|x 1996-1944
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| 852 |
4 |
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|a RU-ToGU
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| 856 |
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|u http://vital.lib.tsu.ru/vital/access/manager/Repository/koha:001002552
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|a статья
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|c 1002552
|d 1002552
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