Influence of perhalophenyl groups in the TADF mechanism of diphosphino gold(I) complexes

Influence of perhalophenyl groups in the TADF mechanism of diphosphino gold(I) complexes

New perhalophenyl three-coordinated gold(i) complexes using the chelate ligand 1,2-bis(diphenyl-phosphino)benzene (dppBz) and [AuR(tht)] (R = C6F5 (1), o-C6BrF4 (2), p-C6BrF4 (3), o-C6F4I (4), p-C6F4I (5); tht = tetrahydrothiophene) have been prepared. The crystal structures of compounds 1 and 2 con...

Full description

Bibliographic Details
Published in:Journal of materials chemistry Vol. 10, № 12. P. 4894-4904
Other Authors: Soldevilla, Inés, García-Camacho, Aimara, Nasibullin, Rinat T., Olmos, M. Elena, Monge, Miguel, Sundholm, Dage, Valiev, Rashid R., López-de-Luzuriaga, José M., Rodríguez-Castillo, María
Format: Article
Language:English
Subjects:
хелатные комплексы
лиганды
флуоресценция
статьи в журналах
Online Access:http://vital.lib.tsu.ru/vital/access/manager/Repository/koha:001002957
LEADER 02239nab a2200385 c 4500
001 koha001002957
005 20230608174216.0
007 cr |
008 230605|2022 enk s a eng d
024 7 |a 10.1039/d1tc04905d  |2 doi 
035 |a koha001002957 
040 |a RU-ToGU  |b rus  |c RU-ToGU 
245 1 0 |a Influence of perhalophenyl groups in the TADF mechanism of diphosphino gold(I) complexes  |c I. Soldevilla, A. García-Camacho, R. T. Nasibullin [et al.] 
336 |a Текст 
337 |a электронный 
504 |a Библиогр.: 36 назв. 
520 3 |a New perhalophenyl three-coordinated gold(i) complexes using the chelate ligand 1,2-bis(diphenyl-phosphino)benzene (dppBz) and [AuR(tht)] (R = C6F5 (1), o-C6BrF4 (2), p-C6BrF4 (3), o-C6F4I (4), p-C6F4I (5); tht = tetrahydrothiophene) have been prepared. The crystal structures of compounds 1 and 2 consist of distorted three-coordinated Au(i) complexes displaying different Au-P distances at the same gold atom. The complexes show intense photoluminescent emission in the solid state at room temperature (RT) and at 77 K. The study of the dependence of the emission lifetime with temperature suggests the existence of thermally activated delayed fluorescence (TADF) processes at RT. We have computed the rate constants for intersystem crossing and reverse intersystem crossing of the photophysical processes through first-principle calculations, supporting the experimental observations with very good agreement. 
653 |a хелатные комплексы 
653 |a лиганды 
653 |a флуоресценция 
655 4 |a статьи в журналах 
700 1 |a Soldevilla, Inés 
700 1 |a García-Camacho, Aimara 
700 1 |a Nasibullin, Rinat T. 
700 1 |a Olmos, M. Elena 
700 1 |a Monge, Miguel 
700 1 |a Sundholm, Dage 
700 1 |a Valiev, Rashid R. 
700 1 |a López-de-Luzuriaga, José M. 
700 1 |a Rodríguez-Castillo, María 
773 0 |t Journal of materials chemistry  |d 2022  |g Vol. 10, № 12. P. 4894-4904  |x 2050-7526 
852 4 |a RU-ToGU 
856 4 |u http://vital.lib.tsu.ru/vital/access/manager/Repository/koha:001002957 
908 |a статья 
999 |c 1002957  |d 1002957 

Similar Items