Synthesis and growth of rare earth borates NaSrR(BO3)2 (R = Ho− Lu, Y, Sc)

NaSrR(BO3)2(R = Ho-Lu, Y, Sc) compounds were obtained for the first time. Their structures exhibit disordered positions of Sr2+and Na+ atoms while RO6polyhedra are connected through the BO3 groups. Large distances between R atoms and high transparency in the range of 250-900 nm make them promising f...

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Bibliographic Details
Published in:	Inorganic chemistry Vol. 61, № 19. P. 7497-7505
Other Authors:	Kuznetsov, Artem B., Kokh, Konstantin A., Sagatov, Nursultan, Gavryushkin, Pavel N., Molokeev, Maxim S., Svetlichnyi, Valerii A., Lapin, Ivan N., Kononova, Nadezda G., Shevchenko, Vyacheslav S., Bolatov, Asset, Uralbekov, Bolat, Goreiavcheva, Anastasia A., Kokh, Alexander E.
Format:	Article
Language:	English
Subjects:	бораты редкоземельных элементов синтез и выращивание монокристаллы статьи в журналах
Online Access:	http://vital.lib.tsu.ru/vital/access/manager/Repository/koha:001003547

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Summary:	NaSrR(BO3)2(R = Ho-Lu, Y, Sc) compounds were obtained for the first time. Their structures exhibit disordered positions of Sr2+and Na+ atoms while RO6polyhedra are connected through the BO3 groups. Large distances between R atoms and high transparency in the range of 250-900 nm make them promising for phosphor applications. A pathway to obtain single crystals was shown by growing NaSrY(BO3)2and NaSrYb-(BO3)2by the top seeded solution growth method with Na2O-B2O3-NaFflux.
Bibliography:	Библиогр.: 51 назв.
ISSN:	0020-1669

Synthesis and growth of rare earth borates NaSrR(BO3)2 (R = Ho− Lu, Y, Sc)

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