Synthesis and growth of rare earth borates NaSrR(BO3)2 (R = Ho− Lu, Y, Sc)

NaSrR(BO3)2(R = Ho-Lu, Y, Sc) compounds were obtained for the first time. Their structures exhibit disordered positions of Sr2+and Na+ atoms while RO6polyhedra are connected through the BO3 groups. Large distances between R atoms and high transparency in the range of 250-900 nm make them promising f...

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Published in:Inorganic chemistry Vol. 61, № 19. P. 7497-7505
Other Authors: Kuznetsov, Artem B., Kokh, Konstantin A., Sagatov, Nursultan, Gavryushkin, Pavel N., Molokeev, Maxim S., Svetlichnyi, Valerii A., Lapin, Ivan N., Kononova, Nadezda G., Shevchenko, Vyacheslav S., Bolatov, Asset, Uralbekov, Bolat, Goreyavcheva, Anastasia A., Kokh, Alexander E.
Format: Article
Language:English
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Online Access:http://vital.lib.tsu.ru/vital/access/manager/Repository/koha:001003547
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245 1 0 |a Synthesis and growth of rare earth borates NaSrR(BO3)2 (R = Ho− Lu, Y, Sc)  |c A. B. Kuznetsov, K. A. Kokh, N. Sagatov [et al.] 
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520 3 |a NaSrR(BO3)2(R = Ho-Lu, Y, Sc) compounds were obtained for the first time. Their structures exhibit disordered positions of Sr2+and Na+ atoms while RO6polyhedra are connected through the BO3 groups. Large distances between R atoms and high transparency in the range of 250-900 nm make them promising for phosphor applications. A pathway to obtain single crystals was shown by growing NaSrY(BO3)2and NaSrYb-(BO3)2by the top seeded solution growth method with Na2O-B2O3-NaFflux. 
653 |a бораты редкоземельных элементов 
653 |a синтез и выращивание 
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655 4 |a статьи в журналах  |9 888921 
700 1 |a Kuznetsov, Artem B.  |9 506271 
700 1 |a Kokh, Konstantin A.  |9 89168 
700 1 |a Sagatov, Nursultan  |9 888923 
700 1 |a Gavryushkin, Pavel N.  |9 888924 
700 1 |a Molokeev, Maxim S.  |9 95853 
700 1 |a Svetlichnyi, Valerii A.  |9 562988 
700 1 |a Lapin, Ivan N.  |9 100086 
700 1 |a Kononova, Nadezda G.  |9 809611 
700 1 |a Shevchenko, Vyacheslav S.  |9 809612 
700 1 |a Bolatov, Asset  |9 809615 
700 1 |a Uralbekov, Bolat  |9 809614 
700 1 |a Goreyavcheva, Anastasia A.  |9 990209 
700 1 |a Kokh, Alexander E.  |9 809610 
773 0 |t Inorganic chemistry  |d 2022  |g Vol. 61, № 19. P. 7497-7505  |x 0020-1669 
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