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20231103125502.0 |
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231030|2022 xxu s a eng d |
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|a 10.1134/s1024856022060069
|2 doi
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|a koha001008918
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|a RU-ToGU
|b rus
|c RU-ToGU
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|a Laser-induced fluorescence of PO photofragments of organophosphates
|c S. M. Bobrovnikov, E. V. Gorlov, V. I. Zharkov, A. D. Safyanov
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|a Текст
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|a электронный
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|a Библиогр.: 34 назв.
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|a The spectrum of phosphorus monoxide (PO) fluorescence is calculated. It is shown that the use of excitation radiation at wavelengths near the bandheads of the (P22 + Q12) and P12 branches of the A2Σ+ (v′ = 0) − X2Π3/2 (v′′ = 0) band provides a spectral separation of the γ (0, 1) PO fluorescence band and the vibrational–rotational Raman spectrum of oxygen. The spectra of the γ (0, 1) fluorescence band of PO fragments of dimethylmethylphosphonate and the vibrational-rotational band of spontaneous Raman scattering on atmospheric oxygen molecules are experimentally obtained under exposure to KrF-laser radiation at a wavelength of 247.78 nm. It is shown that the shape and position of the fluorescence spectra calculated agree well with the experimental data.
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|a фосфорорганические соединения
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|a лазерная фрагментация
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|a оксид фосфора
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|a лазерно-индуцированная флуоресценция
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|a статьи в журналах
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|a Bobrovnikov, Sergei M.
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|a Gorlov, Evgeny V.
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|a Zharkov, Viktor I.
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|a Safyanov, A. D.
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| 773 |
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|t Atmospheric and oceanic optics
|d 2022
|g Vol. 35, № 6. P. 639-644
|x 1024-8560
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|a RU-ToGU
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|u http://vital.lib.tsu.ru/vital/access/manager/Repository/koha:001008918
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|a статья
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|d 1008918
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