Estimation of the limiting sensitivity of laser fragmentation/laser-induced fluorescence technique for detection of nitrocompound vapors in atmosphere

The limiting sensitivity of a technique for detecting vapors of nitrocompounds in the atmosphere based on laser fragmentation/laser-induced fluorescence is estimated in calculations with the developed kinetic model of the LF/LIF process. The calculations take into account the influence of atmospheri...

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Bibliographic Details
Published in:Atmospheric and oceanic optics Vol. 36, № 1. P. 70-77
Main Author: Bobrovnikov, Sergei M.
Other Authors: Gorlov, Evgeny V., Zharkov, Viktor I.
Format: Article
Language:English
Subjects:
Online Access:http://vital.lib.tsu.ru/vital/access/manager/Repository/koha:001017464
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520 3 |a The limiting sensitivity of a technique for detecting vapors of nitrocompounds in the atmosphere based on laser fragmentation/laser-induced fluorescence is estimated in calculations with the developed kinetic model of the LF/LIF process. The calculations take into account the influence of atmospheric nitrogen dioxide as a limiting factor of the sensitivity of the technique in a real atmosphere. It is shown that if the concentration of nitrogen dioxide in the atmosphere does not exceed 10 ppb, the minimum detectable concentrations of nitrobenzene and o-nitrotoluene vapors are the ppb-level. It is also shown that the one-color excitation technique usually used for the detection of nitrocompounds does not allow attaining the maximal LF/LIF efficiency. 
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700 1 |a Zharkov, Viktor I.  |9 883475 
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