Growth and characterization of Na3R(BO3)2 (R = La-Gd) borates: crystal structure, high-temperature behavior, and optical properties
Na3R(BO3)2 (R = La-Gd) borates, grown with Na2O-B2O3-NaF flux, crystallize in the space group P21/n. Contrary to previously published data, the peaks in the 980(La)-950(Gd) °C range are attributed to phase transition process, while the melting process occurs at about 100° higher. Another feature of...
| Published in: | CrystEngComm Vol. 25, № 19. P. 2914-2924 |
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| Other Authors: | , , , , , , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Online Access: | http://vital.lib.tsu.ru/vital/access/manager/Repository/koha:001133153 Перейти в каталог НБ ТГУ |
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| 245 | 1 | 0 | |a Growth and characterization of Na3R(BO3)2 (R = La-Gd) borates: crystal structure, high-temperature behavior, and optical properties |c A. B. Kuznetsov, A. Y. Jamous, V. A. Svetlichnyi [et al.] |
| 336 | |a Текст | ||
| 337 | |a электронный | ||
| 520 | 3 | |a Na3R(BO3)2 (R = La-Gd) borates, grown with Na2O-B2O3-NaF flux, crystallize in the space group P21/n. Contrary to previously published data, the peaks in the 980(La)-950(Gd) °C range are attributed to phase transition process, while the melting process occurs at about 100° higher. Another feature of thermal behavior consists of the gradual decomposition of the compound into Na3R2(BO3)3. The end member in the decomposition series is Na2R2O(BO3)2, which originates under oxygen/water atmosphere. In addition, the components of the thermal expansion tensor and the dependings of the unit-cell parameters of Na3-Nd(BO3)2 on temperature were defined. A series of Pr3+, Nd3+, and Sm3+-doped Na3Gd(BO3)2 (NGB) borates were prepared from mixtures of grown crystals by solid-state synthesis, and their photoluminescence properties were studied in detail. The excitation and emission spectra of NGB: Pr3+ and NGB: Nd3+ are comparable with similar compounds, and the relative intensity reaches the maximum at 1 mol% of Pr3+, Sm3+, and 10 mol.% for Nd3+ doping. | |
| 653 | |a бораты | ||
| 653 | |a высокотемпературное поведение | ||
| 653 | |a термическое поведение | ||
| 653 | |a фотолюминесцентные свойства | ||
| 655 | 4 | |a статьи в журналах |9 957352 | |
| 700 | 1 | |a Kuznetsov, Artem B. |9 506271 | |
| 700 | 1 | |a Jamous, Ammar Y. |9 809617 | |
| 700 | 1 | |a Svetlichnyi, Valerii A. |9 562988 | |
| 700 | 1 | |a Volkov, Sergey N. |9 957353 | |
| 700 | 1 | |a Korolkov, Ilya V. |9 106406 | |
| 700 | 1 | |a Kokh, Konstantin A. |9 89168 | |
| 700 | 1 | |a Gorelova, Liudmila A. |9 957354 | |
| 700 | 1 | |a Krzhizhanovskaya, Maria G. |9 957355 | |
| 700 | 1 | |a Aksenov, Sergey M. |9 440144 | |
| 700 | 1 | |a Kokh, Alexander E. |9 809610 | |
| 773 | 0 | |t CrystEngComm |d 2023 |g Vol. 25, № 19. P. 2914-2924 |x 1466-8033 | |
| 852 | 4 | |a RU-ToGU | |
| 856 | 4 | |u http://vital.lib.tsu.ru/vital/access/manager/Repository/koha:001133153 | |
| 856 | |y Перейти в каталог НБ ТГУ |u https://koha.lib.tsu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=1133153 | ||
| 908 | |a статья | ||
| 039 | |b 100 | ||
| 999 | |c 1133153 |d 1133153 | ||