Green photoluminescence in TbxSc1-xBO3 solid solution

A wide range of solid solutions based on TbBO3 (with ScBO3 ≤ 30 mol%) and ScBO3 (with TbBO3 ≤ 50 mol%) was found in the TbBO3-ScBO3 system. Under UV excitation the characteristic green emission is visible due to the typical 5D4-7F5 transition of Tb3+. The intensity of photoluminescence significantly...

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Published in:Journal of luminescence Vol. 275. P. 120768 (1-8)
Other Authors: Kokh, Alexander E., Kuznetsov, Artem B., Svetlichnyi, Valerii A., Rakhmanova, M. I., Klimov, A. O., Kokh, Konstantin A.
Format: Article
Language:English
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Online Access:https://vital.lib.tsu.ru/vital/access/manager/Repository/koha:001158347
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245 1 0 |a Green photoluminescence in TbxSc1-xBO3 solid solution  |c A. E. Kokh, A. B. Kuznetsov, V. A. Svetlichnyi [et al.] 
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520 3 |a A wide range of solid solutions based on TbBO3 (with ScBO3 ≤ 30 mol%) and ScBO3 (with TbBO3 ≤ 50 mol%) was found in the TbBO3-ScBO3 system. Under UV excitation the characteristic green emission is visible due to the typical 5D4-7F5 transition of Tb3+. The intensity of photoluminescence significantly depends on the doping concentration of Tb3+ and the optimal concentration has been determined as x = 0.05. Crucial impact of hydrogen treatment on the luminescent properties was found. The compositions of TbxSc1-xBO3 (x = 0.05-0.1), after being treated with hydrogen at a temperature of 800 ◦C, has high potential for practical application as a green phosphor. This is due to its impressive quantum yield value of up to 69 % when excited by a 378 nm. 
653 |a зеленая фотолюминесценция 
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655 4 |a статьи в журналах 
700 1 |a Kokh, Alexander E.  |9 809610 
700 1 |a Kuznetsov, Artem B.  |9 506271 
700 1 |a Svetlichnyi, Valerii A.  |9 562988 
700 1 |a Rakhmanova, M. I.  |9 990211 
700 1 |a Klimov, A. O.  |9 990212 
700 1 |a Kokh, Konstantin A.  |9 89168 
773 0 |t Journal of luminescence  |d 2024  |g Vol. 275. P. 120768 (1-8)  |x 0022-2313 
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