Solid solutions in EuSc3(BO3)4-GdSc3(BO3)4 system: Phase diagram, synthesis, crystal growth, structure and luminescence
Solid solutions based on (Eu,Gd)Sc3(BO3)4 (C2/c) and Gd0.25Sc0.75BO3 (R 3) in the EuSc3(BO3)4-GdSc3(BO3)4 system were studied. Synthesis at 1250 ◦C provides wide homogeneity regions which are stable at room temperature. Melt-solution crystallization of both compounds from LiBO2-LiF flux was shown. A...
| Опубликовано в: : | Journal of crystal growth Vol. 645. P. 127842 (1-6) |
|---|---|
| Другие авторы: | , , , , , , , |
| Формат: | Статья в журнале |
| Язык: | English |
| Предметы: | |
| Online-ссылка: | https://vital.lib.tsu.ru/vital/access/manager/Repository/koha:001158348 Перейти в каталог НБ ТГУ |
| LEADER | 02379nab a2200445 c 4500 | ||
|---|---|---|---|
| 001 | koha001158348 | ||
| 005 | 20250627155551.0 | ||
| 007 | cr | | ||
| 008 | 250530|2024 ne s a eng d | ||
| 024 | 7 | |a 10.1016/j.jcrysgro.2024.127842 |2 doi | |
| 035 | |a koha001158348 | ||
| 040 | |a RU-ToGU |b rus |c RU-ToGU | ||
| 245 | 1 | 0 | |a Solid solutions in EuSc3(BO3)4-GdSc3(BO3)4 system: Phase diagram, synthesis, crystal growth, structure and luminescence |c A. E. Kokh, A. B. Kuznetsov, E. Khan [et al.] |
| 336 | |a Текст | ||
| 337 | |a электронный | ||
| 504 | |a Библиогр.: 41 назв. | ||
| 506 | |a Ограниченный доступ | ||
| 520 | 3 | |a Solid solutions based on (Eu,Gd)Sc3(BO3)4 (C2/c) and Gd0.25Sc0.75BO3 (R 3) in the EuSc3(BO3)4-GdSc3(BO3)4 system were studied. Synthesis at 1250 ◦C provides wide homogeneity regions which are stable at room temperature. Melt-solution crystallization of both compounds from LiBO2-LiF flux was shown. All the obtained samples have luminescence characteristic of Eu3+ with a largest peak at 615 nm corresponding to the 5D0 → 7F2 transition. In this series the luminescence intensity monotonically increases with an increase of Eu content. The largest quantum yield of luminescence (53 %) in the EuSc3(BO3)4 GdSc3(BO3)4 system is demonstrated by EuSc3(BO3)4 sample. | |
| 653 | |a люминесценция | ||
| 653 | |a квантовый выход | ||
| 653 | |a редкоземельные бораты | ||
| 653 | |a твердые растворы | ||
| 653 | |a рост кристаллов | ||
| 655 | 4 | |a статьи в журналах | |
| 700 | 1 | |a Kokh, Alexander E. |9 809610 | |
| 700 | 1 | |a Kuznetsov, Artem B. |9 506271 | |
| 700 | 1 | |a Khan, Elona |9 990213 | |
| 700 | 1 | |a Simonova, Ekaterina A. |9 502770 | |
| 700 | 1 | |a Ryadun, Alexey A. |9 990214 | |
| 700 | 1 | |a Lapin, Ivan N. |9 100086 | |
| 700 | 1 | |a Svetlichnyi, Valerii A. |9 562988 | |
| 700 | 1 | |a Kokh, Konstantin A. |9 89168 | |
| 773 | 0 | |t Journal of crystal growth |d 2024 |g Vol. 645. P. 127842 (1-6) |x 0022-0248 | |
| 852 | 4 | |a RU-ToGU | |
| 856 | 4 | |u https://vital.lib.tsu.ru/vital/access/manager/Repository/koha:001158348 | |
| 856 | |y Перейти в каталог НБ ТГУ |u https://koha.lib.tsu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=1158348 | ||
| 908 | |a статья | ||
| 942 | |2 udc | ||
| 039 | |b 100 | ||
| 999 | |c 1158348 |d 1158348 | ||