Synthesis, structural, thermal, and electronic properties of palmierite-related double molybdate α-Cs2Pb(MoO4)2
Cs2Pb(MoO4)2 crystals were prepared by crystallization from their own melt, and the crystal structure has been studied in detail. At 296 K, the molybdate crystallizes in the low-temperature α-form and has a monoclinic palmierite-related superstructure (space group C2/m, a = 2.13755(13) nm, b = 1.231...
| Published in: | Inorganic chemistry Vol. 56, № 6. P. 3276-3286 |
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| Other Authors: | , , , , , , , , , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Online Access: | http://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000585650 Перейти в каталог НБ ТГУ |
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| 008 | 171018|2017 xxu s a eng dd | ||
| 024 | 7 | |a 10.1021/acs.inorgchem.6b02653 |2 doi | |
| 035 | |a to000585650 | ||
| 039 | 9 | |a 201710270727 |b 100 |c 201710181552 |d VLOAD |y 201710181529 |z Александр Эльверович Гилязов | |
| 040 | |a RU-ToGU |b rus |c RU-ToGU | ||
| 245 | 1 | 0 | |a Synthesis, structural, thermal, and electronic properties of palmierite-related double molybdate α-Cs2Pb(MoO4)2 |c S. F. Solodovnikov, V. V. Atuchin, Z. A. Solodovnikova [et.al.] |
| 504 | |a Библиогр.: 57 назв. | ||
| 520 | 3 | |a Cs2Pb(MoO4)2 crystals were prepared by crystallization from their own melt, and the crystal structure has been studied in detail. At 296 K, the molybdate crystallizes in the low-temperature α-form and has a monoclinic palmierite-related superstructure (space group C2/m, a = 2.13755(13) nm, b = 1.23123(8) nm, c = 1.68024(10) nm, β = 115.037(2)°, Z = 16) possessing the largest unit cell volume, 4.0066(4) nm3, among lead-containing palmierites. The compound undergoes a distortive phase transition at 635 K and incongruently melts at 943 K. The electronic structure of α-Cs2Pb(MoO4)2 was explored by using X-ray emission spectroscopy (XES) and X-ray photoelectron spectroscopy methods. For α-Cs2Pb(MoO4)2, the photoelectron core-level and valence-band spectra and the XES band representing the energy distribution of Mo 4d and O 2p states were recorded. Our results allow one to conclude that the Mo 4d and O 2p states contribute mainly to the central part and at the top of the valence band, respectively, with also significant contributions throughout the whole valence-band region of the molybdate under consideration. | |
| 653 | |a двойной молибдат | ||
| 653 | |a пальмиерит | ||
| 653 | |a синтез | ||
| 653 | |a структурные свойства | ||
| 655 | 4 | |a статьи в журналах |9 879358 | |
| 700 | 1 | |a Solodovnikov, Sergey F. |9 441102 | |
| 700 | 1 | |a Atuchin, Victor V. |9 95830 | |
| 700 | 1 | |a Solodovnikova, Zoya A. |9 441103 | |
| 700 | 1 | |a Khyzhun, Oleg Y. |9 409922 | |
| 700 | 1 | |a Danylenko, Mykola I. |9 478300 | |
| 700 | 1 | |a Pishchur, Denis P. |9 478301 | |
| 700 | 1 | |a Plyusnin, Pavel E. |9 478302 | |
| 700 | 1 | |a Pugachev, Alexey M. |9 441104 | |
| 700 | 1 | |a Gavrilova, Tatiana A. |9 103805 | |
| 700 | 1 | |a Eliseev, Aleksander P. |9 853063 | |
| 700 | 1 | |a Reshak, Ali H. |9 428742 | |
| 700 | 1 | |a Alahmed, Zeyad A. |9 428744 | |
| 700 | 1 | |a Habubi, Nadir F. |9 478303 | |
| 773 | 0 | |t Inorganic chemistry |d 2017 |g Vol. 56, № 6. P. 3276-3286 |x 0020-1669 | |
| 852 | 4 | |a RU-ToGU | |
| 856 | 7 | |u http://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000585650 | |
| 856 | |y Перейти в каталог НБ ТГУ |u https://koha.lib.tsu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=427881 | ||
| 908 | |a статья | ||
| 999 | |c 427881 |d 427881 | ||