Development of layered anode structures supported over Apatite-type Solid Electrolytes

Apatite-type lanthanum silicates (ATLS) materials have attracted interest in recent literature as solid electrolytes for SOFCs. The fabrication of an ATLS based fuel cell with the state-of-art electrodes (NiO/YSZ as anode and LSCF or LSM as cathode) can show degradation after long operation hours du...

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Bibliographic Details
Published in:MATEC Web of conferences Vol. 41. P. 04001 (1-4)
Other Authors: Pandis, P., Sadykov, Vladislav A., Stathopoulos, V. N., Kharlamova, Tamara S.
Format: Article
Language:English
Subjects:
Online Access:http://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000624958
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024 7 |a 10.1051/matecconf/20164104001  |2 doi 
035 |a to000624958 
039 9 |a 201807241324  |c 201804270955  |d cat202  |c 201804161541  |d VLOAD  |y 201804161530  |z Александр Эльверович Гилязов 
040 |a RU-ToGU  |b rus  |c RU-ToGU 
245 1 0 |a Development of layered anode structures supported over Apatite-type Solid Electrolytes  |c P. Pandis, T. S. Kharlamova, V. A. Sadykov, V. N. Stathopoulos 
504 |a Библиогр.: 12 назв. 
520 3 |a Apatite-type lanthanum silicates (ATLS) materials have attracted interest in recent literature as solid electrolytes for SOFCs. The fabrication of an ATLS based fuel cell with the state-of-art electrodes (NiO/YSZ as anode and LSCF or LSM as cathode) can show degradation after long operation hours due to Si diffusion mainly towards the anode. In this work, we report a "layer-by-layer anodic electrodes" fabrication by means of spin coating and physical spraying. The overall aim of this work is the successful fabrication of such a layered structure including suitable blocking layers towards the inhibition of Si interdiffusion from the apatite electrolyte to the anode. The results showed that the deposition of 3 layers of LFSO/GDC (3μm), NiO/GDC (4μm) and the final NiO/YSZ anode layer provided a stable half-cell, with no solid state reaction occurring among the electrodes and no Si diffusion observed towards the anode after thermal treatment at 800°C for 120h. 
653 |a твердые электролиты 
653 |a силикаты лантана со структурой апатита 
653 |a анодные электроды 
655 4 |a статьи в журналах  |9 879358 
700 1 |a Pandis, P.  |9 482562 
700 1 |a Sadykov, Vladislav A.  |9 99161 
700 1 |a Stathopoulos, V. N.  |9 482563 
700 1 |a Kharlamova, Tamara S.  |9 99160 
773 0 |t MATEC Web of conferences  |d 2016  |g Vol. 41. P. 04001 (1-4)  |x 2261-236X 
852 4 |a RU-ToGU 
856 7 |u http://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000624958 
856 |y Перейти в каталог НБ ТГУ  |u https://koha.lib.tsu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=434718 
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999 |c 434718  |d 434718