Kinetic model for UV/H2O2 degradation of 8-methoxypsoralen

The influence of Н2О2 on the degradation of 8-methoxypsoralen (8-MOP) in water-ethanol solutions under the action of KrCl and XeBr excilamp radiation in a photoreactor is investigated. A kinematic model of photodegradation of the investigated molecule is constructed. In water-ethanol solutions the a...

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Bibliographic Details
Published in:Proceedings of SPIE Vol. 10614 : XIII International conference on atomic and molecular pulsed lasers, September 10-15, 2017, Tomsk, Russia. P. 1061422-1-1061422-7
Main Author: Tchaikovskaya, Olga N.
Other Authors: Bryantseva, Natalya G., Krayukhina, Vlada S.
Format: Article
Language:English
Subjects:
Online Access:http://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000646048
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520 3 |a The influence of Н2О2 on the degradation of 8-methoxypsoralen (8-MOP) in water-ethanol solutions under the action of KrCl and XeBr excilamp radiation in a photoreactor is investigated. A kinematic model of photodegradation of the investigated molecule is constructed. In water-ethanol solutions the addition of Н2О2 altered the mechanism of decay of 8-MOP under the action of a KrCl excilamp in comparison with irradiation by a XeBr excilamp. This behavior is explained by the fact that the action of 283 nm radiation leads to accumulation of a stable photoproduct. In order to establish the toxicity of this product further research is needed. 
653 |a 8-метоксипсорален 
653 |a фурокумарины 
653 |a эксилампы 
653 |a фотоиндуцированная деградация 
655 4 |a статьи в журналах  |9 879358 
700 1 |a Bryantseva, Natalya G.  |9 100907 
700 1 |a Krayukhina, Vlada S.  |9 483831 
773 0 |t Proceedings of SPIE  |d 2018  |g Vol. 10614 : XIII International conference on atomic and molecular pulsed lasers, September 10-15, 2017, Tomsk, Russia. P. 1061422-1-1061422-7  |x 0277-786X 
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