Zinc oxide films obtained by sol-gel method from film-forming solutions

Thin ZnO films on silicon and quartz substrates were obtained from a film-enriched ethanolic solution based on Zn(NO3)2⋅6H2O and salicylic acid. The effect of salicylic acid on the processes occurring in the film-forming solution was studied by IR spectroscopy, proton-magnetic resonance, and viscome...

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Bibliographic Details
Published in:Journal of Physics: Conference Series Vol. 1145. P. 012020 (1-8)
Main Author: Kuznetsova, Svetlana A.
Other Authors: Mongush, E., Lisitsa, Konstantin V.
Format: Article
Language:English
Subjects:
Online Access:http://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000707525
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Summary:Thin ZnO films on silicon and quartz substrates were obtained from a film-enriched ethanolic solution based on Zn(NO3)2⋅6H2O and salicylic acid. The effect of salicylic acid on the processes occurring in the film-forming solution was studied by IR spectroscopy, proton-magnetic resonance, and viscometry methods. The formation of zinc salicylate nitrate in an ethanol solution is established, where salicylic acid exhibits a monodentate property in the carboxyl group. Thermal formation of zinc oxide was determined by thermal analysis and X-ray diffraction. The analysis of optical and electrophysical characteristics of ZnO films was carried out using spectroscopy, ellipsometry and also a block for measuring the electrophysical properties of thin-film materials. It was found that ZnO films were semiconductors of the electronic type, characterized by an optical band gap of 2.91-3.21eV, a surface resistance of 109-106 Q. and transparency coefficients in the visible spectral range of 0.80-0.96. It was shown that as the thickness of the ZnO films increased the resistance decreased.
Bibliography:Библиогр.: 13 назв.
ISSN:1742-6588