Synthesis and growth of new rare earth borates KCaR(BO3)2 (R= La, Pr and Nd)
Novel KCaR(BO3)2 (R ¼ La, Pr and Nd) compounds have been obtained by solid-state synthesis. Specifically, single crystals of KCaNd(BO3)2 and KCaPr(BO3)2 were grown by using a top seeded solution growth method from the KBO2 flux. These crystal compounds belong to the orthorhombic system, Pbca space...
| Опубликовано в: : | Journal of solid state chemistry Vol. 282. P. 121091 (1-5) |
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| Другие авторы: | , , , , , , , |
| Формат: | Статья в журнале |
| Язык: | English |
| Предметы: | |
| Online-ссылка: | http://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000794660 Перейти в каталог НБ ТГУ |
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| 024 | 7 | |a 10.1016/j.jssc.2019.121091 |2 doi | |
| 035 | |a to000794660 | ||
| 039 | 9 | |a 202103051435 |c 202103031643 |d VLOAD |y 202103031629 |z Александр Эльверович Гилязов | |
| 040 | |a RU-ToGU |b rus |c RU-ToGU | ||
| 245 | 1 | 0 | |a Synthesis and growth of new rare earth borates KCaR(BO3)2 (R= La, Pr and Nd) |c A. B. Kuznetsov, K. A. Kokh, N. G. Kononova [et al.] |
| 336 | |a Текст | ||
| 337 | |a электронный | ||
| 504 | |a Библиогр.: 34 назв. | ||
| 520 | 3 | |a Novel KCaR(BO3)2 (R ¼ La, Pr and Nd) compounds have been obtained by solid-state synthesis. Specifically, single crystals of KCaNd(BO3)2 and KCaPr(BO3)2 were grown by using a top seeded solution growth method from the KBO2 flux. These crystal compounds belong to the orthorhombic system, Pbca space group. KCaLa(BO3)2 exhibits high transparency in the range of 200-900 nm. Pr and Nd compounds have a strong emission bands that are related to the well-known electron transition of Pr3þ (3P0 → 3H6 at 630 nm, 3P0 → 3F2 at 670 nm) and Nd3þ (4F3/2 → 4I9/2 at 875 nm, 4F3/2 → 4I11/2 at 1054 nm). | |
| 653 | |a рост кристаллов | ||
| 653 | |a синтез в твердом состоянии | ||
| 653 | |a бораты редкоземельных элементов | ||
| 653 | |a люминесценция | ||
| 655 | 4 | |a статьи в журналах |9 879358 | |
| 700 | 1 | |a Kokh, Konstantin A. |9 89168 | |
| 700 | 1 | |a Kononova, Nadezda G. |9 809611 | |
| 700 | 1 | |a Shevchenko, Vyacheslav S. |9 809612 | |
| 700 | 1 | |a Kaneva, Ekaterina V. |9 809619 | |
| 700 | 1 | |a Uralbekov, Bolat |9 809614 | |
| 700 | 1 | |a Kokh, Alexander E. |9 809610 | |
| 700 | 1 | |a Kuznetsov, Artem B. |9 506271 | |
| 700 | 1 | |a Svetlichnyi, Valerii A. |9 562988 | |
| 773 | 0 | |t Journal of solid state chemistry |d 2020 |g Vol. 282. P. 121091 (1-5) |x 0022-4596 | |
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| 856 | 4 | |u http://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000794660 | |
| 856 | |y Перейти в каталог НБ ТГУ |u https://koha.lib.tsu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=479091 | ||
| 908 | |a статья | ||
| 999 | |c 479091 |d 479091 | ||