Influence of the method of preparation of the Pd-Bi/Al2O3 catalyst on catalytic properties in the reaction of liquid-phase oxidation of glucose into gluconic acid
Gluconic acid and its derivatives are extensively used in pharmaceutical, food, textile, and pulp and paper branches of industry during production of food additives, cleansers, medicinal drugs, stabilizers, etc. To obtain gluconic acid, the method of conversion of glucose into gluconic acid by mol...
| Published in: | Catalysts Vol. 10, № 3. P. 271 (1-21) |
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| Other Authors: | , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Online Access: | http://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000794759 Перейти в каталог НБ ТГУ |
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| 024 | 7 | |a 10.3390/catal10030271 |2 doi | |
| 035 | |a to000794759 | ||
| 039 | 9 | |a 202103051650 |b 100 |c 202103041712 |d VLOAD |y 202103041708 |z Александр Эльверович Гилязов | |
| 040 | |a RU-ToGU |b rus |c RU-ToGU | ||
| 245 | 1 | 0 | |a Influence of the method of preparation of the Pd-Bi/Al2O3 catalyst on catalytic properties in the reaction of liquid-phase oxidation of glucose into gluconic acid |c M. P. Sandu, V. S. Sidelnikov, A. A. Geraskin [et al.] |
| 336 | |a Текст | ||
| 337 | |a электронный | ||
| 504 | |a Библиогр.: 52 назв. | ||
| 520 | 3 | |a Gluconic acid and its derivatives are extensively used in pharmaceutical, food, textile, and pulp and paper branches of industry during production of food additives, cleansers, medicinal drugs, stabilizers, etc. To obtain gluconic acid, the method of conversion of glucose into gluconic acid by molecular oxygen in the presence of solid catalysts is promising. The process of obtaining Pd and bimetallic nanoparticles Pd-Bi, coated on Al2O3, has been considered in the work. Samples were prepared by combined and successive impregnation of the Al2O3 support using metalloorganic precursors Pd(acac)2, Bi(ac)3, and dissolved in an organic solvent (acetic acid), followed by the removal of excess solvent. To achieve the formation of Pd and bimetallic nanoparticles Pd-Bi on the substrate surface, the synthesized samples were subjected to thermal decomposition sequentially in the atmosphere of Ar, O2, and H2. The surface of the obtained catalysts was studied by a combination of physicochemical methods of analysis. The catalysts were analyzed in the reaction of liquid phase oxidation of glucose. The best results are achieved in the presence of the catalyst obtained by combined impregnation. | |
| 653 | |a окисление глюкозы | ||
| 653 | |a глюконовая кислота | ||
| 653 | |a биметаллические катализаторы | ||
| 653 | |a палладий-висмут | ||
| 653 | |a жидкофазное окисление | ||
| 655 | 4 | |a статьи в журналах |9 879358 | |
| 700 | 1 | |a Sidelnikov, Vladimir S. |9 510776 | |
| 700 | 1 | |a Geraskin, Andrej A. |9 510777 | |
| 700 | 1 | |a Chernyavskii, Aleksandr V. |9 510778 | |
| 700 | 1 | |a Kurzina, Irina A. |9 99208 | |
| 700 | 1 | |a Sandu, Mariya Petrovna |9 799962 | |
| 773 | 0 | |t Catalysts |d 2020 |g Vol. 10, № 3. P. 271 (1-21) |x 2073-4344 | |
| 852 | 4 | |a RU-ToGU | |
| 856 | 4 | |u http://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000794759 | |
| 856 | |y Перейти в каталог НБ ТГУ |u https://koha.lib.tsu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=480299 | ||
| 908 | |a статья | ||
| 999 | |c 480299 |d 480299 | ||