On the evaporation dynamics of trinitrotoluene microparticles on the glass surface

The results of measuring the time dependence of the concentration of trinitrotoluene (TNT) vapor over its solid microconcentrations on the glass surface with a low TNT concentration on the surface of 100 ng/cm2 are presented. Such microconcentrations of traces are typical for the conditions of anti-...

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Bibliographic Details
Published in:International journal of energetic materials and chemical propulsion Vol. 20, № 3. P. 17-25
Other Authors: Tivileva, M. I., Gruznov, V. M., Baldin, M. N., Vorozhtsov, Alexander B., Kikhtenko, A. V., Titov, Sergey S.
Format: Article
Language:English
Subjects:
Online Access:http://vital.lib.tsu.ru/vital/access/manager/Repository/koha:000894051
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024 7 |a 10.1615/IntJEnergeticMaterialsChemProp.2021038342  |2 doi 
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245 1 0 |a On the evaporation dynamics of trinitrotoluene microparticles on the glass surface  |c M. I. Tivileva, V. M. Gruznov, M. N. Baldin [et al.] 
336 |a Текст 
337 |a электронный 
504 |a Библиогр.: c. 24-25 
520 3 |a The results of measuring the time dependence of the concentration of trinitrotoluene (TNT) vapor over its solid microconcentrations on the glass surface with a low TNT concentration on the surface of 100 ng/cm2 are presented. Such microconcentrations of traces are typical for the conditions of anti-terrorist control of objects for the presence of TNT. The measurements were made using a portable multicapillary gas chromatograph (GC) EKHO-V-IDTS (Russia) with TNT vapor concentration. The threshold for determining the concentration of TNT vapor by the EKHO-V-IDTS gas chromatograph corresponds to the modern level and is equal to 10-14 g/cm3. Vapor sampling is performed by a vortex sampling device (VSD), which is used in the anti-terrorist control of objects. It is shown that the initial surface concentration of TNT traces of 100 ng/cm2 on the glass surface decreases to 12 ng/cm2 in a time of 2.6 h due to evaporation into an open half-space under laboratory conditions. The vapor concentration over the residual TNT concentration of 12 ng/cm2 corresponds to the GC sensitivity threshold for TNT vapor concentration equal to 10-14 g/cm3. 
653 |a тринитротолуол 
653 |a время испарения 
653 |a испарение микрочастиц 
653 |a поверхность стекла 
655 4 |a статьи в журналах  |9 879358 
700 1 |a Tivileva, M. I.  |9 804150 
700 1 |a Gruznov, V. M.  |9 804152 
700 1 |a Baldin, M. N.  |9 804153 
700 1 |a Vorozhtsov, Alexander B.  |9 104481 
700 1 |a Kikhtenko, A. V.  |9 804154 
700 1 |a Titov, Sergey S.  |9 355890 
773 0 |t International journal of energetic materials and chemical propulsion  |d 2021  |g Vol. 20, № 3. P. 17-25  |x 2150-766X 
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