Study of an SmBO3-ScBO3 system and new SmSc(BO3)2 orthoborate

A new SmSc(BO3)2 compound was discovered from the study of SmBO3-ScBO3 by solid-state synthesis. The obtained compound was grown from a stoichiometric melt by a spontaneous crystallization method, and crystallizes in the space group R3¯ with the cell parameters of a = 4.8951(6) Å and c = 16.3012(2)...

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Published in:CrystEngComm Vol. 23, № 6. P. 1482-1488
Other Authors: Kuznetsov, Artem B., Kokh, Konstantin A., Kononova, Nadezda G., Shevchenko, Vyacheslav S., Rashchenko, Sergey V., Lapin, Ivan N., Svetlichnyi, Valerii A., Uralbekov, Bolat, Bolatov, Asset, Simonova, Ekaterina A., Kokh, Alexander E.
Format: Article
Language:English
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Online Access:http://vital.lib.tsu.ru/vital/access/manager/Repository/koha:000897789
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520 3 |a A new SmSc(BO3)2 compound was discovered from the study of SmBO3-ScBO3 by solid-state synthesis. The obtained compound was grown from a stoichiometric melt by a spontaneous crystallization method, and crystallizes in the space group R3¯ with the cell parameters of a = 4.8951(6) Å and c = 16.3012(2) Å. In addition, phase equilibria in this system in the 900-1300 °C temperature range were studied by X-ray diffraction and thermal analyses, as well as special diffusion experiments. 
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700 1 |a Kuznetsov, Artem B.  |9 506271 
700 1 |a Kokh, Konstantin A.  |9 89168 
700 1 |a Kononova, Nadezda G.  |9 809611 
700 1 |a Shevchenko, Vyacheslav S.  |9 809612 
700 1 |a Rashchenko, Sergey V.  |9 809613 
700 1 |a Lapin, Ivan N.  |9 100086 
700 1 |a Svetlichnyi, Valerii A.  |9 562988 
700 1 |a Uralbekov, Bolat  |9 809614 
700 1 |a Bolatov, Asset  |9 809615 
700 1 |a Simonova, Ekaterina A.  |9 502770 
700 1 |a Kokh, Alexander E.  |9 809610 
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