Investigation of 4,6-di(hetero)aryl-substituted pyrimidines as emitters for non-doped OLED and laser dyes

Two novel V-shaped push-pull systems based on a pyrimidine acceptor have been designed and investigated. Low-temperature measurements of the fluorescence and delayed luminescence spectra demonstrated that the emission bands of the compounds have a charge-transfer character. Despite the fact that...

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Bibliographic Details
Published in:Journal of photochemistry and photobiology A: Chemistry Vol. 408. P. 113089 (1-9)
Other Authors: Dinastiya, Ekaterina M., Verbitskiy, Egor V., Gadirov, Ruslan M., Samsonova, Lyubov G., Degtyarenko, Konstantin M., Grigoryev, Denis V., Kurtcevich, Alexander E., Solodova, Tatyana A., Telminov, Evgenii N., Rusinov, Gennady L., Chupakhin, Oleg, Charushin, Valery N.
Format: Article
Language:English
Subjects:
Online Access:http://vital.lib.tsu.ru/vital/access/manager/Repository/koha:000923442
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245 1 0 |a Investigation of 4,6-di(hetero)aryl-substituted pyrimidines as emitters for non-doped OLED and laser dyes  |c E. M. Dinastiya, E. V. Verbitskiy, R. M. Gadirov [et al.] 
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520 3 |a Two novel V-shaped push-pull systems based on a pyrimidine acceptor have been designed and investigated. Low-temperature measurements of the fluorescence and delayed luminescence spectra demonstrated that the emission bands of the compounds have a charge-transfer character. Despite the fact that compounds in thermal vacuum deposition films have a low fluorescence quantum yield, OLED devices based on them show high efficiency, which can be associated with the emission mechanism through delayed fluorescence. It is found that photoproducts, obtaining upon exposure to UV-irradiation of fluorophores in chloroform solution, exhibit laser activity in the red region of the spectrum. 
653 |a пиримидины 
653 |a лазерные красители 
653 |a органические светодиоды 
655 4 |a статьи в журналах  |9 879358 
700 1 |a Dinastiya, Ekaterina M.  |9 851771 
700 1 |a Verbitskiy, Egor V.  |9 851773 
700 1 |a Gadirov, Ruslan M.  |9 95832 
700 1 |a Samsonova, Lyubov G.  |9 106560 
700 1 |a Degtyarenko, Konstantin M.  |9 99501 
700 1 |a Grigoryev, Denis V.  |9 101525 
700 1 |a Kurtcevich, Alexander E.  |9 851774 
700 1 |a Solodova, Tatyana A.  |9 132558 
700 1 |a Telminov, Evgenii N.  |9 94668 
700 1 |a Rusinov, Gennady L.  |9 437929 
700 1 |a Chupakhin, Oleg  |9 449989 
700 1 |a Charushin, Valery N.  |9 437930 
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