Laser preparation of bimetallic Au-Pt nanoparticles for modification of dark TiO2 photocatalyst

Bimetallic Au-Pt nanoparticles with different molar ratios were obtained using laser synthesis (Nd:YAG laser with the parameters: 1064 nm, 180 mJ, 7 ns, and 20 Hz). The bimetallic nature of the particles was confirmed by X-ray diffraction and UV-visible spectroscopy. According to the transmission el...

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Опубликовано в: :Bulletin of the Russian Academy of Sciences: Physics Vol. 88, suppl. № 2. P. S154-S159
Другие авторы: Fakhrutdinova, Elena D., Krainyukova, M. A, Volokitina, A. V., Svetlichnyi, Valerii A.
Формат: Статья в журнале
Язык:English
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245 1 0 |a Laser preparation of bimetallic Au-Pt nanoparticles for modification of dark TiO2 photocatalyst  |c E. D. Fakhrutdinova, M. A. Krainyukova, A. V. Volokitina, V. A. Svetlichnyi  
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520 3 |a Bimetallic Au-Pt nanoparticles with different molar ratios were obtained using laser synthesis (Nd:YAG laser with the parameters: 1064 nm, 180 mJ, 7 ns, and 20 Hz). The bimetallic nature of the particles was confirmed by X-ray diffraction and UV-visible spectroscopy. According to the transmission electron microscopy data, it was found that the bimetallic nanoparticles were represented by the alloy particles of an elongated shape with a diameter of 5-10 nm. Then, the bimetallic particles were decorated with a powder of highly defective dark titania by impregnation.The photocatalytic activity of the TiO₂ with deposited bimetallic particles was estimated in the reactions of Rhodamine B dye decomposition and hydrogen production under LED irradiation with a wavelength of 375 nm. It was found that the highest photocatalytic activity in the series was exhibited by the samples with the deposited bimetallic particles, where the Au : Pt ratios was 50 : 50 and 30 : 70. It was also shown that the TiO₂ nanoparticles decorated with the bimetallic Au : Pt NPs exhibited higher activity compared to the samples successively modified with monometals in the same ratios. 
653 |a биметаллические наночастицы 
653 |a импульсная лазерная абляция 
653 |a фотокатализ 
655 4 |a статьи в журналах 
700 1 |a Fakhrutdinova, Elena D.  |9 567766 
700 1 |a Krainyukova, M. A  |9 980644 
700 1 |a Volokitina, A. V.  |9 798732 
700 1 |a Svetlichnyi, Valerii A.  |9 562988 
773 0 |t Bulletin of the Russian Academy of Sciences: Physics  |d 2024  |g Vol. 88, suppl. № 2. P. S154-S159  |x 1062-8738 
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