Luminescence solvato-and vapochromism of alkynyl-phosphine copper clusters

The reaction of [Cu(NCMe)4][PF6] with aromatic acetylenes HC2R and triphosphine 1,1,1-tris(diphenylphosphino)methane in the presence of NEt3 results in the formation of hexanuclear Cu(I) clusters with the general formula [Cu6(C2R)4{(PPh2)3CH}2][PF6]2 (R = 4-X-C6H4 (1-5) and C5H4N (6); X = NMe2 (1),...

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Bibliographic Details
Published in:Inorganic chemistry Vol. 54, № 17. P. 8288-8297
Corporate Author: Томский государственный университет Физический факультет Научные подразделения ФФ
Other Authors: Krytchankou, Ilya S., Gurzhiy, Vladislav V., Pomogaev, Vladimir A., Tunik, Sergey P., Koshevoy, Igor O.
Format: Article
Language:English
Subjects:
Online Access:http://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000525284
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