Luminescence solvato-and vapochromism of alkynyl-phosphine copper clusters
The reaction of [Cu(NCMe)4][PF6] with aromatic acetylenes HC2R and triphosphine 1,1,1-tris(diphenylphosphino)methane in the presence of NEt3 results in the formation of hexanuclear Cu(I) clusters with the general formula [Cu6(C2R)4{(PPh2)3CH}2][PF6]2 (R = 4-X-C6H4 (1-5) and C5H4N (6); X = NMe2 (1),...
Published in: | Inorganic chemistry Vol. 54, № 17. P. 8288-8297 |
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Corporate Author: | |
Other Authors: | , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Online Access: | http://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000525284 Перейти в каталог НБ ТГУ |